Carbonaceous Materials-12: a Novel Highly Sensitive Graphene Oxide-Based Carbon Electrode: Preparation, Characterization, and Heavy Metal Analysis in Food Samples

Yavuz S., Erkal A., KARİPER I. A., SOLAK A. O., JEON S., Mulazimoglu I. E., ...More

FOOD ANALYTICAL METHODS, vol.9, no.2, pp.322-331, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 9 Issue: 2
  • Publication Date: 2016
  • Doi Number: 10.1007/s12161-015-0198-3
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.322-331
  • Keywords: Differential pulse anodic stripping voltammetry, Graphene oxide modified glassy carbon electrode, Lead and cadmium analysis, Food samples, STRIPPING VOLTAMMETRIC DETERMINATION, ELEMENT REFERENCE VALUES, EUROPEAN-COMMUNITY, BISMUTH, NANOPARTICLES, INHABITANTS, CADMIUM, TISSUES, URINE, BLOOD
  • Erciyes University Affiliated: Yes


Graphene oxide (GO) was covalently attached to glassy carbon (GC) electrode (GC-O-GO) for fabricating nanosensors to determine trace Pb2+ and Cd2+ using differential pulse anodic stripping voltammetry (DPASV). Surface characterization of the nanofilm-covered electrode was performed via electrochemical cyclic voltammetry (CV), transmission electron microscopy (TEM), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) techniques. Surface pKa of the GO covalent attached GC (GC-O-GO) was calculated via CV. Under optimal conditions, a linear response was found for Pb2+ and Cd2+ in the range from 1 x 10(-8) to 1 x 10(-12) M. The limit of detections (LODs) of Pb2+ and Cd2+ were 0.25 pM and 0.28 pM, respectively. The method shows good reproducibility, and stability was successfully applied to measure Pb2+ and Cd2+ levels in rice, soya, milk, and tap water samples, with good agreement with those obtained by the standard inductively coupled plasma optical emission spectrometry (ICP-OES) method. The method was evaluated by application with the simultaneous determination of the ions in food samples (n = 6) using the standard addition method. The recoveries of the Pb2+ and Cd2+ were up to 98 %.