Inhibition Effects of Amides on the Corrosion of Copper in 1.0 M HCl: Theoretical and Experimental Studies

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Zor S., Saraçoğlu M., Kandemirli F., Arslan T.

CORROSION, cilt.67, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 67
  • Basım Tarihi: 2011
  • Doi Numarası: 10.5006/1.3665357
  • Dergi Adı: CORROSION
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: acid solutions, copper, corrosion, polarization, MILD-STEEL CORROSION, HYDROCHLORIC-ACID SOLUTIONS, SODIUM-CHLORIDE SOLUTIONS, AERATED SULFURIC-ACID, 0.5 M H2SO4, ANODIC-DISSOLUTION, NACL SOLUTIONS, SCHIFF-BASES, FILMS, MEDIA
  • Erciyes Üniversitesi Adresli: Evet

Özet

The corrosion inhibition effects of benzamide (BA) and 4-aminobenzenesulfonamide (ABSA) for copper in 1.0 M hydrochloric acid (HCl) solution were investigated using potentiodynamic polarization, cyclic voltammetry (CV), and potentiostatic current-time curves. The Langmuir adsorption isotherms of the inhibitors were used to explain the adsorption behavior. In addition, surface analysis of copper was investigated using scanning electron microscopy (SEM). The results showed that the inhibition efficiency of ABSA was much better than those of BA. The theoretical study on the corrosion inhibition efficiencies for neutral and protonated forms of the BA and ABSA molecules were performed using density functional theory (DFT) and MP2 method in gas and water phases.

The corrosion inhibition effects of benzamide (BA) and 4-aminobenzenesulfonamide (ABSA) for copper in 1.0 M hydrochloric acid (HCl) solution were investigated using potentiodynamic polarization, cyclic voltammetry (CV), and potentiostatic current-time curves. The Langmuir adsorption isotherms of the inhibitors were used to explain the adsorption behavior. In addition, surface analysis of copper was investigated using scanning electron microscopy (SEM). The results showed that the inhibition efficiency of ABSA was much better than those of BA. The theoretical study on the corrosion inhibition efficiencies for neutral and protonated forms of the BA and ABSA molecules were performed using density functional theory (DFT) and MP2 method in gas and water phases.