Microwave Synthesis of Ag@MoS2 in NADES medium for the Dispersive Micro Solid Phase Extraction of Atrazine in environmental samples

UZCAN F., SOYLAK M.

Water, Air, and Soil Pollution, vol.236, no.6, 2025 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 236 Issue: 6
  • Publication Date: 2025
  • Doi Number: 10.1007/s11270-025-07991-3
  • Journal Name: Water, Air, and Soil Pollution
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, ABI/INFORM, Agricultural & Environmental Science Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), Artic & Antarctic Regions, BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Compendex, Environment Index, Geobase, Greenfile, Pollution Abstracts, Veterinary Science Database, Civil Engineering Abstracts
  • Keywords: Ag@MoS2, Atrazine, Microwave synthesis, NADES, Preconcentration, Spheres, Spice samples
  • Erciyes University Affiliated: Yes

Abstract

A simple-to-operate, environmentally friendly method has been developed for novel Ag sphere synthesis in NADES media to achieve spherical form and for green synthesis that was modified with MoS2 nanoparticles. Ag@MoS2 was designed as an adsorbent for a rapid and economical dispersive micro solid phase extraction approach at trace levels. The Analytical parameters pH (5.0), sorbent mass (10 mg), extraction time (2.5 min), eluent volume (5 mL), eluent type (acetonitrile), and sample volume (10 mL) were optimized. The detection limit was found to be 0.6 μg L–1 and the technique’s linearity ranged from 2.1 to 250 μg L–1. The suggested approach has several benefits, including selectivity, precision, and rapidity. It is used practically to identify ATZ in lake water, fish farming water, tap water, allspice and rosehip. The ATZ recovery was sufficient, averaging between 91 and 107%. The method had an overall score of 0.57 on the AGREE scale.