Synthesis of mesoporous magnetic Fe<sub>3</sub>O<sub>4</sub> nanoparticles with different pore sizes and investigation of dye adsorption capacities

Ulusal F., Bilici Z., Ozay Y., Özdemir N., Dizge N.

PARTICULATE SCIENCE AND TECHNOLOGY, vol.42, no.5, pp.804-814, 2024 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 5
  • Publication Date: 2024
  • Doi Number: 10.1080/02726351.2023.2291770
  • Journal Name: PARTICULATE SCIENCE AND TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Applied Science & Technology Source, Aquatic Science & Fisheries Abstracts (ASFA), Chemical Abstracts Core, Communication Abstracts, Compendex, Computer & Applied Sciences, INSPEC, Metadex, Pollution Abstracts, Civil Engineering Abstracts
  • Page Numbers: pp.804-814
  • Keywords: Mesoporous magnetic Fe3O4 nanoparticles, BR18 dye, dye adsorption
  • Erciyes University Affiliated: Yes

Abstract

This study synthesized mesoporous magnetic Fe3O4 nanoparticles with two pore sizes. First, two different pore sizes of SiO2 were synthesized using polyethylene glycol with molecular weights of 6000 kDa and 35,000 kDa. Next, mesoporous SiO2 was used as a template, and Fe3O4 was coated with a precursor. Then, the silica present in mesoporous SiO2 was leached. The adsorption capacities of the prepared mesoporous magnetic Fe3O4-NPs were compared using an azo cationic dye, Basic Red 18. Parameters such as solution pH, adsorbent amount, and dye concentration were optimized in the adsorption experiments. Additionally, the reusability of Fe3O4-NPs was investigated. The optimum conditions for P6-Fe3O4-NPs were the original pH, 0.5 g/L dose, 50 ppm dye concentration, 60 min contact time, and 100% removal efficiency. For P35-Fe3O4-NPs, the optimal conditions were original pH, 0.75 g/L dose, 20 ppm dye concentration, and 60 min of contact time, with 100% removal efficiency. The second-order kinetic model and Langmuir isotherm were found to be suitable for describing the adsorption of both nanoparticles. Under the optimum conditions, complete dye removal efficiency was achieved for both nanomaterials. Furthermore, in the real wastewater, the adsorption experiment utilizing P6-Fe3O4-NPs yielded a 98% efficiency in color removal at 620 nm.