Determination of some trace metals with a new synthesized polymer resin by FAAS in various tea and herbal plants samples

Dasbasi T., Soykan C., Cankaya N., ÜLGEN A.

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, cilt.55, sa.6, ss.466-473, 2018 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 55 Sayı: 6
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1080/10601325.2018.1470464
  • Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.466-473
  • Anahtar Kelimeler: FAAS, Solid phase extraction, Synthesized polymer resin, Trace metals, Herbal plants, SOLID-PHASE EXTRACTION, ATOMIC-ABSORPTION-SPECTROMETRY, MULTIWALLED CARBON NANOTUBES, FOOD SAMPLES, ENVIRONMENTAL-SAMPLES, WATER SAMPLES, EMISSION-SPECTROMETRY, FE3O4 NANOPARTICLES, CHELATING RESIN, HEAVY-METALS
  • Erciyes Üniversitesi Adresli: Evet

Özet

In this work, a new polymer resin with a functional groups capable of holding trace metals has been synthesized. The structure of polymer resin has been examined by BET-N-2 method analyzer, IR spectrometer, scanning electron microscope (SEM) and elemental microanalyser. The synthesized polymer resin was used for the simultaneous separation and preconcentration of the trace metals from various tea and herbal plants samples. After extraction process, flame atomic absorption spectrometry (FAAS) was used to determine the trace metals. The analytical parameters and solid phase extraction (SPE) performance such as pH, sample volume, flow rates of sample, flow rates of eluent, concentration, volume and type of eluent and effect of interference ions, were investigated. The limits of detection (DL) of the SPE procedure for trace metals, were calculated to be (3s) in the range of 0.9-4.0g L-1 (n = 21) and the factors of preconcentration (PF) were obtained at 200 for Cd, Co, Cu, Fe, Ni and Zn, and at 50 for Cr, Mn and Pb ions and the relative standard deviation (RSD) at 2% (n = 11).