2-(3,5-Dioxo-4-azatricyclo[,6)]-dec-8-en-4-yl)acetic acid

AKKURT M. , Jarrahpour A., Shirvani P., Tahir M. N.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.69, 2013 (ESCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 69
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1107/s1600536813021764


The asymmetric unit of the title compound, C11H11NO4, contains two molecules, A and B, with different conformations: in molecule A, the norborne and carboxylic acid groups lie to the same side of the heterocycle, whereas in a molecule B, they lie on opposite sides. In the crystal, the A molecules form R-2(2)(8) carboxylic acid inversion dimers, linked by pairs of O-H center dot center dot center dot O hydrogen bonds. The B molecules link to one of the ketone O atoms of the A molecule by an O-H center dot center dot center dot O interaction, resulting in tetramers (two A and two B molecules). The tetramers are linked by weak C-H center dot center dot center dot O interactions, generating a three-dimensional network.