Solid-Phase Extraction of Some Heavy Metal Ions on a Double-Walled Carbon Nanotube Disk and Determination by Flame Atomic Absorption Spectrometry

Karatepe A., SOYLAK M., Elci L.

JOURNAL OF AOAC INTERNATIONAL, cilt.94, sa.5, ss.1617-1624, 2011 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 94 Sayı: 5
  • Basım Tarihi: 2011
  • Doi Numarası: 10.5740/jaoacint.10-388
  • Dergi Adı: JOURNAL OF AOAC INTERNATIONAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1617-1624
  • Erciyes Üniversitesi Adresli: Evet

Özet

A new preconcentration method was developed for the determination of trace amounts of Cu(II), Fe(III), Pb(II), Ni(II), and Cd(II) on a double-walled carbon nanotube disk. 4-(2-Thiazolylazo) resorcinol was used as a complexing reagent. The effects of parameters, including pH of the solutions, amounts of complexing reagent, eluent type, sample volume, flow rates of solutions, and matrix ions were examined for quantitative recoveries of the studied analyte ions. The retained metal ions were eluted by 2 M HNO3. The LOD values for the analytes were in the range of 0.7-4.4 mu g/mL. Natural water samples and standard reference materials were analyzed by the presented method.