Determination of some metal ions in various meat and baby food samples by atomic spectrometry

Dasbasi T., SAÇMACI Ş., ÜLGEN A., KARTAL Ş.

FOOD CHEMISTRY, cilt.197, ss.107-113, 2016 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 197
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.foodchem.2015.10.093
  • Dergi Adı: FOOD CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.107-113
  • Anahtar Kelimeler: Solid phase extraction, Heavy metal ion, Chelating resin, Atomic spectrometry, Food samples, SOLID-PHASE EXTRACTION, CLOUD-POINT EXTRACTION, ABSORPTION-SPECTROMETRY, TRACE-ELEMENTS, WATER SAMPLES, SELECTIVE EXTRACTION, AMBERLITE XAD-16, FISH SAMPLES, ZN(II) IONS, PRECONCENTRATION
  • Erciyes Üniversitesi Adresli: Evet

Özet

In this paper, we report a simple and rapid solid phase extraction system for the separation/preconcentration and determination of Cd(II), Co(II), Cu(II), Fe(III), Cr(III), Pb(II), and Zn(II) ions by flame atomic absorption spectrometry (FAAS). This method is based upon the retention of metal ions on a column packed with poly[N-(3-methyl-1H-indole-1-yl)]-2-methacrylamide-co-2-acrylamido-2-methyl-1-pro pane sulphonic acid-co divinylbenzene] (MMAD) resin as a solid-phase extraction (SPE) sorbent at pH 8. At the optimized conditions, the limits of detection (3s/b) between 0.12 and 1.6 mu g L-1, preconcentration factor of 100, and the relative standard deviation of <= 1.8% were achieved (n = 10). The accuracy of the method was verified by analyzing certified reference materials (CRMs) and performing recovery experiments. The developed method was successfully applied to the various natural water, meat products and baby food samples. The recoveries of analyte ions were found in added real samples and CRMs from 95% to 102%. (C) 2015 Elsevier Ltd. All rights reserved.