Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile


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AKKURT M. , Horton P. N. , Younes S. H. H. , Mohamed S. K. , Albayati M. R.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.71, 2015 (Journal Indexed in ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 71
  • Publication Date: 2015
  • Doi Number: 10.1107/s2056989015012566
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Abstract

In the title compound, C20H14N2O2, the hydroxybenzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)degrees. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds link the molecules into a supramolecular layer in the bc plane; N-H center dot center dot center dot pi interactions also contribute to this arrangement. The layers are linked by weak by C-H center dot center dot center dot pi and pi-pi [inter-centroid separation = 3.8713 (7) angstrom] interactions.