Crystal structure and Hirshfeld surface analysis of 4-{2,2-dichloro-1 -[(E)-(4-chlorophenyl)diazenyl]-ethenyl}-N,N-dimethylaniline


Atioglu Z., AKKURT M. , Shikhaliyev N. Q. , Mukhtarova S. H. , Suleymanova G. T. , Toze F. A. A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.76, ss.1033-1047, 2020 (ESCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 76
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1107/s2056989020007549
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Sayfa Sayıları: ss.1033-1047

Özet

The title compound, C16H14Cl3N3, comprises three molecules of similar shape in the asymmetric unit. The crystal cohesion is ensured by intermolecular C-H center dot center dot center dot N and C-H center dot center dot center dot Cl hydrogen bonds in addition to C-Cl center dot center dot center dot pi interactions. Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that Cl center dot center dot center dot H/H center dot center dot center dot Cl (33.6%), H center dot center dot center dot H (27.9%) and C center dot center dot center dot H/H center dot center dot center dot C (17.6%) are the most important contributors towards the crystal packing.