Crystal structure and Hirshfeld surface analysis of 4-{2,2-dichloro-1 -[(E)-(4-chlorophenyl)diazenyl]-ethenyl}-N,N-dimethylaniline

Atioglu, Zeliha; AKKURT, MEHMET; Shikhaliyev, Namiq; Mukhtarova, Sevinc; Suleymanova, Gulnar; Toze, Flavien

doi:10.1107/s2056989020007549

Crystal structure and Hirshfeld surface analysis of 4-{2,2-dichloro-1 -[(E)-(4-chlorophenyl)diazenyl]-ethenyl}-N,N-dimethylaniline

Atioglu Z., AKKURT M., Shikhaliyev N. Q., Mukhtarova S. H., Suleymanova G. T., Toze F. A. A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.76, ss.1033-1047, 2020 (ESCI, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 76
Basım Tarihi: 2020
Doi Numarası: 10.1107/s2056989020007549
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
Sayfa Sayıları: ss.1033-1047
Erciyes Üniversitesi Adresli: Evet

Özet

The title compound, C16H14Cl3N3, comprises three molecules of similar shape in the asymmetric unit. The crystal cohesion is ensured by intermolecular C-H center dot center dot center dot N and C-H center dot center dot center dot Cl hydrogen bonds in addition to C-Cl center dot center dot center dot pi interactions. Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that Cl center dot center dot center dot H/H center dot center dot center dot Cl (33.6%), H center dot center dot center dot H (27.9%) and C center dot center dot center dot H/H center dot center dot center dot C (17.6%) are the most important contributors towards the crystal packing.