Simultaneous preconcentration of trace metals in environmental samples using amberlite XAD-2010/8-hydroxyquinoline system

gündoğdu A., DURAN C., Senturk H. B., ELÇİ L., Soylak M.

ACTA CHIMICA SLOVENICA, cilt.54, sa.2, ss.308-316, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 54 Sayı: 2
  • Basım Tarihi: 2007
  • Dergi Adı: ACTA CHIMICA SLOVENICA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.308-316
  • Anahtar Kelimeler: amberlite XAD-2010, solid phase extraction, preconcentration, FAAS, ATOMIC-ABSORPTION-SPECTROMETRY, SOLID-PHASE EXTRACTION, WATER SAMPLES, HEAVY-METALS, SOLVENT-EXTRACTION, NICKEL, LEAD, COPPER, CADMIUM, SEPARATION
  • Erciyes Üniversitesi Adresli: Evet

Özet

A simple and sensitive system for simultaneous preconcentration of Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Pb(II) and Cd(II) at trace level by flame atomic absorption spectrometry (FAAS) is proposed. Amberlite XAD-2010 packed in a column was used as sorbent. Analyte ions were sorbed in the column as their 8-hydroxyquinoline chelates; they could then be eluted by 1 mol L-1 HNO3 in acetone. The analytical conditions including pH, amounts of 8-hydroxyquinoline, sample volume etc. on the quantitative recoveries of the analytes were investigated. The effects of the concomitants ions on the recoveries of the analytes column were also studied. The detection limits, corresponding to three times the standard deviation of the blank, were found to be in the range of 0.10-0.40 mu g L-1. The accuracy of the procedure was measured by analyte determinations in certified reference materials (CRM NIES No. 7 Tea Leaves and TMDW-500 Drinking Water). The applications of the presented system were performed by the analysis of some environmental samples including water samples.