Methyl (2Z)-2-{(2Z)-3-[(cyclopentylidene) amino]-4-oxo-2-phenylimino1,3-thiazolidin-5-ylidene} acetate

---

Atıf İçin Kopyala

Mague J. T., AKKURT M., Mohamed S. K., Hassan A. A., Albayati M. R.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.70, 2014 (ESCI)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 70
• Basım Tarihi: 2014
• Doi Numarası: 10.1107/s1600536814004048
• Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
• Erciyes Üniversitesi Adresli: Evet

Özet

In the title compound, C17H17N3O3S, the thiazole ring is nearly planar [maximum deviation = 0.015 (1)angstrom for the ring N atom] and the cyclopentane ring has a twist conformation. The molecular conformation is stabilized by a hypervalent interaction between the S atom and the ester group carbonyl O atom, with an S center dot center dot center dot O distance of 2.7931 (10) angstrom. In the crystal, C-H center dot center dot center dot O interactions generate chains of molecules propagating along [110] and pi-pi stacking interactions [centroidcentroid distance = 3.4677 (7) angstrom] between the thiazole rings organize these chains into (001) layers.