Fe3O4-SiO2-MIL-53 (Fe) nanocomposite for magnetic dispersive micro-solid phase extraction of cadmium (II) at trace levels prior to HR-CS-FAAS detection

SOYLAK M., UZCAN F., Goktas O., GÜMÜŞ Z. P.

Food Chemistry, cilt.429, 2023 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 429
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1016/j.foodchem.2023.136855
  • Dergi Adı: Food Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Cadmium, Food samples, Metal organic frameworks, Preconcentration, Water samples
  • Erciyes Üniversitesi Adresli: Evet

Özet

A magnetic metal–organic framework Fe3O4-SiO2-MIL-53 (Fe) nanocomposite was synthesized for magnetic dispersion micro-solid phase extraction (M-d-µSPE) of cadmium in water, spice, chocolate, tea, and tobacco samples prior to the detection by flame atomic absorption spectrometry. Fe3O4-SiO2-MIL-53 (Fe) nanocomposite fabricated using the solvothermal technique was characterized using a field emission scanning electron microscope and X-ray diffraction. The extraction efficiency of the method was improved by optimizing the experimental factors. After optimization, the linearity range for Cd (II) was 4.3–500 µgL-1. The limits of detection and quantification were 1.3 and 4.3 µgL-1, respectively. The presented magnetic dispersion-micro solid phase extraction method was applied to Cd (II) analysis in food and some environmental samples.