Crystal structure and Hirshfeld surface analysis of (Z)-4-oxo-4-{phenyl[(thiophen-2-yl)methyl]amino}but-2-enoic acid
Acta Crystallographica Section E: Crystallographic Communications, cilt.80, sa.Pt 6, ss.572-576, 2024 (ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 80 Sayı: Pt 6
- Basım Tarihi: 2024
- Doi Numarası: 10.1107/s2056989024003967
- Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
- Sayfa Sayıları: ss.572-576
- Anahtar Kelimeler: crystal structure, thiophene ring, hydrogen bonds, disorder, Hirshfeld surface analysis
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Erciyes Üniversitesi Adresli: Evet
Özet
In the title compound, C15H13NO3S, the molecular conformation is stable with the intramolecular O - H...O hydrogen bond forming a S(7) ring motif. In the crystal, molecules are connected by C - H..O hydrogen bonds, forming C(8) chains running along the a-axis direction. Cohesion of the packing is provided by weak van der Waals interactions between the chains. A Hirshfeld surface analysis was undertaken to investigate and quantify the intermolecular interactions. The thiophene ring is disordered in a 0.9466(17):0.0534(17) ratio over two positions rotated by 180°.