THERMOCHEMICAL AND ELECTROCHEMICAL STUDY OF MAGNESIUM INSERTION INTO ALPHA-UO3-X

PATAT S. , DUEBER R., DICKENS P.

SOLID STATE IONICS, cilt.59, ss.151-155, 1993 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 59
  • Basım Tarihi: 1993
  • Doi Numarası: 10.1016/0167-2738(93)90241-t
  • Dergi Adı: SOLID STATE IONICS
  • Sayfa Sayısı: ss.151-155

Özet

A new magnesium insertion compound of the uranium oxide alpha-UO2.95 was synthesized at ambient temperature. The product was characterized structurally by powder X-ray diffraction. Enthalpy of formation was measured calorimetrically. Gibbs free energy of formation and magnesium diffusion coefficients we- determined electrochemically.