Ammonium [(1S)-(endo,anti)]-(-)-3-bromocamphor-8-sulfonate


Abbasi M. A. , Aziz-ur-Rehman A., AKKURT M. , Jahangir M., Ng S. W. , Khan I. U.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.66, 2010 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 66
  • Publication Date: 2010
  • Doi Number: 10.1107/s1600536810022804
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Abstract

In the title molecular salt, NH(4)(+)center dot C(10)H(14)BrO(4)S(+), the norbornane skeleton of the anion is composed of two five-membered rings in envelope conformations and a six-membered ring with one Br atom, one carbonyl O atom and a methyl group held in a boat conformation by a bridging methylene group. Short intramolecular C-H center dot center dot center dot O and C-H center dot center dot center dot Br interactions occur. In the crystal, the component ions are linked by intermolecular N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds.