Crystal structure and Hirshfeld surface analysis of 7-[(6-hydroxy-5,5,8a-trimethyl-2-methylenedecahydronaphthalen-1-yl)methoxy]-2H-chromen-2-one

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Karimli E. G., Khrustalev V. N., AKKURT M., Khalilov A. N., Bhattarai A., Aleskerova A. N., ...Daha Fazla

Acta Crystallographica Section E: Crystallographic Communications, cilt.79, ss.777-781, 2023 (ESCI, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 79
• Basım Tarihi: 2023
• Doi Numarası: 10.1107/s2056989023006552
• Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
• Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
• Sayfa Sayıları: ss.777-781
• Anahtar Kelimeler: crystal structure, Ferula persica, hydrogen bonds, C-H center dot center dot center dot pi interactions, Hirshfeld surface analysis
• Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
• Erciyes Üniversitesi Adresli: Evet

Özet

The title compound, C24H30O4, consists of two trans-fused cyclohexane rings attached to a chromen-2-one moiety through an oxymethylene bridge. The cyclohexane rings adopt half-chair and chair conformations. In the crystal, molecules are linked by C-H...O and O-H...O hydrogen bonds, forming a triperiodic network. Furthermore, C-H...interactions stabilize the crystal structure. A Hirshfeld surface analysis revealed that the most important contributions to the crystal packing are from H...H (56.9%), O...H/H...O (23.0%) and C...H/H...C (19.6%) contacts.