MULTIVARIATE OPTIMIZATION OF PARAMETERS FOR THE DETERMINATION OF THORIUM IN ROCK SAMPLES BY CLOUD POINT EXTRACTION COUPLED TO UV-VISIBLE SPECTROPHOTOMETRY

Jalbani N. B., SOYLAK M., Munshi A., Kazi T. G.

FRESENIUS ENVIRONMENTAL BULLETIN, cilt.23, ss.2304-2309, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 23
  • Basım Tarihi: 2014
  • Dergi Adı: FRESENIUS ENVIRONMENTAL BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2304-2309
  • Anahtar Kelimeler: Cloud point extraction, Th(IV), Rock samples, Arsenazo-III, Factorial design, Uv-visible spectrophotometry, SOLID-PHASE EXTRACTION, RARE-EARTH-ELEMENTS, SIMULTANEOUS PRECONCENTRATION, EMISSION-SPECTROMETRY, OPTODE SPECTRA, TRACE AMOUNTS, URANYL IONS, ICP-MS, URANIUM, SEPARATION
  • Erciyes Üniversitesi Adresli: Evet

Özet

A simple and effective method has been developed for the preconcentration of trace amount of thorium by cloud point extraction (CPE) using arsenazo-Ill as complexing agent prior to its UV-Visible spectrophotometric determination. A placket-burman design (PBD) was used to determine the main factors such as pH (P), amount of triton X-114 (TX-114), cetyltrimethylammonium bromide (CTAB), ligand volume (LV), addition salt (Sty) and temperature (T). Under optimum conditions, the influence of significant variables including pH, TX-114, and LV on the quantitative extraction efficiency of Th (IV) were investigated by Central 2(3) + star composite design (CCD). Interference effect of some anions, cations and some metals was also studied. The limit of detection was found to be 0.46 mu g/L with preconcentration factor of 50. The relative standard deviation of the method was <5%. The method was successfully employed for the determination and preconcentration of thorium in rock sample.