Synthesis and characterization of conducting copolymer of (N (1),N (3)-bis(thiophene-3-ylmethylene)benzene-1,3-diamine-co-3,4-ethylenedioxythiophene)


KUMBUL A., TURAC E., DURSUN T., Sahmetlioglu E.

CHEMICAL PAPERS, cilt.64, ss.114-117, 2010 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 64 Konu: 1
  • Basım Tarihi: 2010
  • Doi Numarası: 10.2478/s11696-009-0087-6
  • Dergi Adı: CHEMICAL PAPERS
  • Sayfa Sayısı: ss.114-117

Özet

Electrochemical copolymerization of N (1),N (3)-bis(thiophene-3-ylmethylene)benzene-1,3-diamine (TMBA) with 3,4-ethylenedioxythiophene (EDOT) was carried out in a CH3CN/LiClO4 (0.1 M) solvent-electrolyte via potentiodynamic electrolysis. Chemical structure of the monomer was determined by nuclear magnetic resonance (H-1 NMR) and Fourier transform infrared (FTIR) spectroscopy. The resulting copolymer was characterized by cyclic voltammetry (CV), FTIR, scanning electron microscopy (SEM), and thermogravimetry analyses (TGA). Conductivity measurements of the copolymer and PEDOT (poly(3,4-ethylenedioxythiophene)) were carried out by the four-probe technique.