2-[(E)-(4-Methylphenyl)iminomethyl]-6-(morpholin-4-ylmethyl)phenol


Creative Commons License

AKKURT M. , Turktekin S., Jarrahpour A., Sharghi H., Badrabady S. A. T. , Aberi M., ...Daha Fazla

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.67, 2011 (SCI İndekslerine Giren Dergi) identifier identifier identifier

  • Cilt numarası: 67
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1107/s1600536810052311
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Özet

In the title compound, C19H22N2O2, the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), theta and phi of 0.5642 (18) angstrom, 177.32 (17) and phi = 10 (4)degrees, respectively. The two benzene rings make a dihedral angle of 42.67 (8)degrees with each other. An intramolecular O-H center dot center dot center dot N hydrogen bond helps to stabilize the molecular conformation. Aromatic C-H center dot center dot center dot pi interactions and pi-pi stacking interactions [centroid-centroid distance = 3.6155 (15) angstrom] between the benzene rings contribute to the stabilization of the crystal structure.