Flame atomic absorption spectrometric determination of Cd, Pb, and Cu in food samples after pre-concentration using 4-(2-thiazolylazo) resorcinol-modified activated carbon

Habila M., YILMAZ E., Alothman Z. A., SOYLAK M.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, cilt.20, sa.6, ss.3989-3993, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20 Sayı: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.jiec.2013.12.101
  • Dergi Adı: JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3989-3993
  • Anahtar Kelimeler: Solid-phase extraction, Activated carbon, Heavy metals, Flame atomic absorption spectrometry, SOLID-PHASE EXTRACTION, TRACE-METAL IONS, WATER SAMPLES, AQUEOUS-SOLUTION, SPECTROPHOTOMETRIC DETERMINATION, FLUORESCENCE SPECTROMETRY, EMISSION-SPECTROMETRY, DROP MICROEXTRACTION, DRINKING-WATER, COLUMN PRIOR
  • Erciyes Üniversitesi Adresli: Evet

Özet

This work aimed to develop a solid-phase extraction method using low-cost activated carbon produced from waste and modified with 4-(2-thiazolylazo) resorcinol for Cd(II), Pb(II), and Cu(II). The results showed that quantitative recovery of analytes was obtained at pH 6 with 3 M nitric acid as the eluent and a sample volume up to 1000 mL. The method was validated using certified reference material and addition-recovery tests. The limits of detection (LODs) for Pb(II), Cd(II), and Cu(II) were 2.03 mu g L-1, 0.15 mu g L-1, and 0.19 mu g L-1, respectively. The procedure was applied for determination of analytes in food samples. (C) 2014 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.