Crystal structure and Hirshfeld surface analysis of (3aR,4S,7S,7aS)-4,5,6,7,8,8-hexachloro-2-{6[(3aR,4R,7R,7aS)-4,5,6,7,8,8-hexachloro-1,3-dioxo- 1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl]hexyl}-3a,4,7,7a-tetrahydro-1H-4,7-methano- isoindole-1,3(2H)-dione

Alikhanova A., Atioglu Z., AKKURT M., Mlowe S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.77, ss.775-784, 2021 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 77
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1107/s2056989021006952
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.775-784
  • Anahtar Kelimeler: crystal structure, pyrrolidine ring, cyclopentane ring, cyclohexane ring, Hirshfeld surface analysis, CATALYTIC-ACTIVITY, CYANOSILYLATION, COMPLEXES, COORDINATION, ALDEHYDES, IRON(III), HYDROGEN
  • Erciyes Üniversitesi Adresli: Evet

Özet

The molecule of the title compound, C24H16Cl12N2O4, is generated by a crystallographic inversion centre at the midpoint of the central C-C bond. A kink in the molecule is defined by a torsion angle of -169.86 (15)degrees about this central bond of the alkyl bridge. The pyrrolidine ring is essentially planar [max. deviation = 0.014 (1) angstrom]. The cyclohexane ring has a boat conformation, while both cyclopentane rings adopt an envelope conformation. In the crystal structure, molecules are linked by intermolecular C-H center dot center dot center dot O, C-H center dot center dot center dot Cl and C-Cl center dot center dot center dot pi interactions, and short intermolecular Cl center dot center dot center dot O and Cl center dot center dot center dot Cl contacts, forming a three-dimensional network.