Novel isatin-Schiff base Cu(II) and Ni(II) complexes. X-ray crystal structure of bis[3-(4-hexylphenylimino)-1H-indol-2(3H)-one]-dichlorocopper(II) complex

Ercag A., Yildirim S., Akkurt M., Ozgur M., Heinemann F.

CHINESE CHEMICAL LETTERS, vol.17, no.2, pp.243-246, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 17 Issue: 2
  • Publication Date: 2006
  • Journal Name: CHINESE CHEMICAL LETTERS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.243-246
  • Erciyes University Affiliated: Yes

Abstract

Schiff base ligand (HL) derived from 4-hexylaniline with isatin (1H-indole-2,3-dione) and its complexes with Cu(II), Ni(II) were prepared and characterized by analytical, spectroscopic (IR, UV-Vis, Mass) techniques, electrical conductivity, magnetic and thermal measurements. The crystal and molecular structure of [Cu(HL)(2)Cl-2] was determined by a single-crystal X-ray diffraction study. The molecular structure of the title compound has an inversion center on the Cu atom.