Crystal structure of {(E)-4-[(1-allyl-1H1,2,3-triazol-4-yl)methoxy] benzylidene}[2-(morpholin-4-yl) ethyl] amine


Celikesir S. T. , AKKURT M. , Jarrahpour A., Chermahini M. M. , Shiri P., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.70, 2014 (ESCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 70
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1107/s1600536814016754
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

In the title compound, C19H25N5O2, the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)degrees, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, molecules are linked via C-H center dot center dot center dot pi interactions, forming slabs lying parallel to (10(1) over bar). The C atoms of the bridging ethylene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13): 0.366 (13).