Determination of Rhodamine B in Cosmetics, Candy, Water, and Plastic by a Novel Multiwalled Carbon Nanotube (MWCNT)@Zinc Oxide@Magnetite Nanocomposite for Magnetic Solid-Phase Extraction (MSPE) with Spectrophotometric Detection

Kizil N., Erbilgin D., Basaran E., Yola M. L., YILMAZ E., Marouch S., ...Daha Fazla

Analytical Letters, cilt.57, sa.7, ss.1182-1196, 2024 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 7
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/00032719.2023.2243353
  • Dergi Adı: Analytical Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1182-1196
  • Anahtar Kelimeler: Magnetic solid phase extraction, multiwalled carbon nanotubes, rhodamine B, spectrophotometry
  • Erciyes Üniversitesi Adresli: Evet

Özet

A new magnetic solid phase microextraction method (MSPE) was developed for the preconcentration of rhodamine B from plastics, cosmetics, and environmental samples before spectrophotometric analysis. A nanocomposite adsorbent containing ZnO nanoparticles (NPs), multi-walled carbon nanotubes (MWCNTs) and Fe3O4 nanoparticles was synthesized by a hydrothermal procedure. The new magnetic nanocomposite (MWCNTs@ZnO@Fe3O4) was characterized by Fourier-transform infrared spectroscopy (FT-IR), x-ray diffraction (XRD), and scanning electron microscopy (SEM). The pH, sample volume, eluent type, adsorbent mass, influence of foreign species, and analyte-adsorbent and eluent contact times were optimized. The optimum pH was 3; adsorbent mass, 20 mg; sample volume, 50 mL; and eluent, 0.7 mL of ethanol. Recovery values exceeding 95% were obtained. The developed vortex assisted magnetic solid phase extraction method (VA-MSPE) was applied to practical analysis. The limits of detection (LOD) and quantification (LOQ) were 0.83 µg L−1 and 2.77 µg L−1, respectively. The addition/recovery experiments were carried on several water samples to demonstrate acceptable recoveries.