Factorial design for multivariate optimization of preconcentration system for spectrophotometric phosphorus determination

DİVRİKLİ Ü., akdoğan a., SOYLAK M., ELÇİ L.

TALANTA, cilt.79, sa.5, ss.1287-1291, 2009 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79 Sayı: 5
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.talanta.2009.05.046
  • Dergi Adı: TALANTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1287-1291
  • Anahtar Kelimeler: Preconcentration, Amberlite XAD-4, Phosphorus, Spectrophotometry, FLOW-INJECTION ANALYSIS, DOEHLERT MATRIX, ONLINE PRECONCENTRATION, EXPERIMENTAL-VARIABLES, NATURAL-WATERS, PHOSPHATE, METHYLMERCURY, SPECTROSCOPY, EXTRACTION, SEPARATION
  • Erciyes Üniversitesi Adresli: Evet

Özet

The present paper proposes a preconcentration procedure for phosphorus determination by using ultraviolet-visible spectrophotometer. It is based on the formation of phosphomolybdate and its reduction to molybdenum blue. Phosphorus extraction as phosphomolybdenum blue complex was performed onto Amberlite XAD-4. The optimization step was carried out using two-level full factorial design. Three variables (resin amount, sample volume, flow rate) were regarded as factors in the optimization. The relative standard deviation was 2% at 0.08 mu g mL(-1). The limit of detection was found to be 2.23 mu g L(-1) (N = 15). The proposed solid-phase extraction procedure was applied to phosphorus in some fruit leaves, natural waters, and a standard reference material (SRM 1515 apple leaves). (C) 2009 Elsevier B.V. All rights reserved.