Structural investigation of bis(4-methyl-1-piperazine-glyoximato)dipyridinato cobalt(III) chloro dinitrate trihydrate

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Ozturk S., Akkurt M., Macit M., Isik S., Fun H.

MOLECULES, vol.10, no.7, pp.767-771, 2005 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 10 Issue: 7
  • Publication Date: 2005
  • Doi Number: 10.3390/10070767
  • Journal Name: MOLECULES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.767-771
  • Keywords: cobalt(III), piperazine, glyoximato
  • Open Archive Collection: AVESIS Open Access Collection
  • Erciyes University Affiliated: Yes

Abstract

The crystal and molecular structure of the title compound, C24H36CoN10O4 center dot 2(NO3)center dot 3(H2O)center dot Cl, have been determined by X-ray analysis: Cc (No: 9), a = 17.6920(4) angstrom, b = 11.8163(2) angstrom, c = 16.4752(4) A, beta = 91.679(1)degrees, Z = 4. The Co(III) ion is six-coordinated with octahedral geometry, the pyridine rings are planar and the piperazine rings assume chair conformations.