Thermal conversion behavior of paper mill sludge: characterization, kinetic, and thermodynamic analyses

Creative Commons License

Yaras A., Demirel B., Akkurt F., Arslanoglu H.

Biomass Conversion and Biorefinery, cilt.13, sa.3, ss.2007-2016, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 13 Sayı: 3
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1007/s13399-020-01232-9
  • Dergi Adı: Biomass Conversion and Biorefinery
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Compendex, INSPEC
  • Sayfa Sayıları: ss.2007-2016
  • Anahtar Kelimeler: Model-free kinetics, Paper mill sludge, Pyrolysis, Thermodynamic parameters, Thermogravimetric analysis
  • Erciyes Üniversitesi Adresli: Evet

Özet

© 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.The present paper reports the pyrolysis behavior, kinetic, and thermodynamic parameters of paper mill sludge (PMS), which is a paper manufacturing residue and cannot be re-evaluated, at three heating rates (5, 10, and 20 °C min−1) under non-isothermal conditions. Ultimate and proximate analyses of the paper mill sludge were carried out. Kinetic and thermodynamic parameters were calculated using four model-free methods; Flynn-Wall Ozawa (FWO), Friedman, Kissinger-Akahira-Sunose (KAS), and distributed activation energy model (DAEM). High R2 values revealed that all models are compatible with TGA data. The activation energy calculated (101.01 kJ mol−1) from FWO was higher than the other three methods. Pre-exponential factor values ranged from 0.56 × 103 and 14.55 × 103 s−1 for all methods. Kinetic and thermodynamic findings will be beneficial in terms of the process design of PMS pyrolysis. Graphical abstract: [Figure not available: see fulltext.]