Determination of trace metal ions by AAS in natural water samples after preconcentration of pyrocatechol violet complexes on an activated carbon column

Narin I., Soylak M., Elçi L., Doğan M.

TALANTA, cilt.52, sa.6, ss.1041-1046, 2000 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 52 Sayı: 6
  • Basım Tarihi: 2000
  • Doi Numarası: 10.1016/s0039-9140(00)00468-9
  • Dergi Adı: TALANTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1041-1046
  • Anahtar Kelimeler: preconcentration, activated carbon column, trace metal, natural waters, AAS, ATOMIC-ABSORPTION SPECTROMETRY, FLOW-INJECTION PRECONCENTRATION, PLASMA-MASS SPECTROMETRY, RARE-EARTH ELEMENTS, X-RAY-FLUORESCENCE, AMBERLITE XAD-2, SEPARATION PROCEDURE, CHELATING FIBER, SEA-WATER, ICP-AES
  • Erciyes Üniversitesi Adresli: Evet

Özet

A simple preconcentration method is described for the determination of Cu, Mn, Co, Cd, Pb, Ni and Cr in water samples by flame AAS. Trace metal ions in water were sorbed as pyrocatechol violet complexes on activated carbon column at the pH range of 4-8, then eluted with 1 M HNO3 in acetone. The effect of major cations and anions of the natural water samples on the sorption of metal ions has been also investigated. The concentration of the metal ions detected after preconcentration was in agreement with the added amount. The present method was found to be applicable to the preconcentration of Cu, Mn, Co, Cd, Pb, Ni and Cr in natural water samples with good results such as R.S.D. from 3 to 8% (N = 10) and detection limits under 70 ng. 1(-1). (C) 2000 Elsevier Science B.V. All rights reserved.