The thermochemistry of LiCuO, Li2CuO2 and LiCu2O2

Patat S. , Blunt D., Chippindale A., Dickens P.

Solid State Ionics, vol.46, pp.325-329, 1991 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 46
  • Publication Date: 1991
  • Doi Number: 10.1016/0167-2738(91)90233-2
  • Title of Journal : Solid State Ionics
  • Page Numbers: pp.325-329

Abstract

The enthalpies of formation of LiCuO, Li2CuO2 and LiCu2O2 have been determined by solution calorimetry to be -390.99 +/- 0.88, -780.65 +/- 2.34 and -555.93 +/- 2.54 kJ mol-1 respectively. The data are used to construct a theoretical Li-Cu-O ternary phase diagram at 298 K.