Crystal structure of bis[N-(3,4,5-trimethoxybenzylidene)-2-mercaptoanilinato] zinc(II)

Ozturk S., İDE S., Oztas S., Ancin N., Tuzun M., Fun H.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.214, no.11, pp.763-765, 1999 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 214 Issue: 11
  • Publication Date: 1999
  • Doi Number: 10.1524/zkri.1999.214.11.763
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.763-765
  • Erciyes University Affiliated: Yes

Abstract

The crystal and molecular structure of bis[N-(3,4,5-trimethoxybenzylidene)-2-mercaptoanilinato] zinc(II), [(C16H16NO3S)(2)Zn], has been determined at room temperature. The compound crystallizes in the tetragonal system, space group P4(2)/n, with unit cell dimensions a = 11.6726(1) Angstrom, c = 24.6274(3) Angstrom, Z = 4 and D-x = 1.326 g.cm(-3). The structure was refined by a full-matrix least-squares procedure on F-2 to final R = 0.0582 using 2921 reflections with I greater than or equal to 2 sigma(I). The zinc atom shows distorted tetrahedral coordination. The five-membered ring adopts envelope conformation.