Synthesis and structural investigation of (4-methoxy-phenyl)-[4-(4-methoxy-phenyl)-1-(1-phenylethylideneamino)-2-thioxo-1,2-dihydro-pyrimidin-5-yl]-methanone

AKKURT M., Saripinar E., OZTURK S., YILMAZ C., FUN H.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, cilt.218, sa.7, ss.488-491, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 218 Sayı: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1524/zkri.218.7.488.20712
  • Dergi Adı: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.488-491
  • Erciyes Üniversitesi Adresli: Evet

Özet

The crystal structure of (4-methoxy-phenyl)-[4-(4-methoxy-phenyl)-1-(1-phenylethylideneamino)-2-thioxo-1,2-dihydro-pyrimidin-5-yl]-methanone, has been determined by single-crystal X-ray diffraction at 183(2) K. The compound crystallizes in the monoclinic system, space group P2(1)/c. The O3 and C19 atoms in the methoxy group shows conformational disorder. In the title compound, the pyrimidine ring is slightly nonplanar. The angle between the planes formed by the ring atoms N2-C2-C3 and C1-N1-C4 is 4.0 (1)degrees. The three phenyl rings form dihedral angles of 147.9 (1), 113.0 (1) and 103.2 (1)degrees with the pyrimidine ring. The structure is stabilized by weak intermolecular C-H...O interactions.