Akademik Veri Yönetim Sistemi
Acta Crystallographica Section E: Crystallographic Communications, cilt.82, ss.480-484, 2026 (ESCI, Scopus)
The title compound, C28H23ClN2O5S, crystallizes with two independent molecules (A and B) in the asymmetric unit. In the central fused ring systems, the pyrrolidine rings adopt envelope conformations and the cyclohexene rings adopt distorted-half chair conformations. In molecules A and B, the least-squares mean planes of the sixteen-membered central ring systems form dihedral angles of 81.5 (1) and 84.0 (1)°, respectively, with the benzene rings attached to the sulfanyl groups, while they make dihedral angles of 18.6 (1) and 7.7 (1)°, respectively, with the chlorobenzene rings. In the crystal, O - H⋯O hydrogen bonds and weak C - H⋯O and C - H⋯Cl interactions link the molecules, forming a three-dimensional network. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9-18] in PLATON. The solvent contribution was not included in the reported molecular weight and density. A Hirshfeld surface analysis indicates that H⋯H (36.8% for molecule A; 29.8% for molecule B), O⋯H/H⋯O (22.1% for A and 27.3% for B), C⋯H/H⋯C (22.1% for A and 20.2% for B) and Cl⋯H/H⋯Cl (9.7% for A and 13.2% for B) interactions are the most important contributors to the crystal packing.