Crystal structure and Hirshfeld surface analysis of bis{(<i>Z</i>)-<i>N</i>′-[(<i>E</i>)-(furan-2-yl)methylidene]carbamohydrazonothioato}nickel(II) methanol disolvate

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Azizova A. N., Mammadova G. Z., Çelikesir S., AKKURT M., Bhattarai A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.79, ss.669-673, 2023 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1107/s2056989023005182
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI)
  • Sayfa Sayıları: ss.669-673
  • Anahtar Kelimeler: crystal structure, distorted square-planar geometry, Hirshfeld surface analysis, hydrogen bonds, ligands
  • Erciyes Üniversitesi Adresli: Evet

Özet

In the title complex, [Ni(C6H6N3OS)(2)]center dot 2CH(3)OH, the Ni-II atom is coordinated by the S and N atoms of two N '-[(Z)-(furan-2-yl)methylidene]carbamohydrazonothioic acid ligands in a distorted square-planar geometry. The two mutual ligands bound to Ni-II are also connected by C-H center dot center dot center dot S interactions, while the H atoms of the NH2 group of the ligands form R-4(4)(8) motifs with the O atoms of the solvent ethyl alcohol molecules. At the same time, the OH groups of the solvent ethyl alcohol molecules form parallel layers to the (011) plane by the O-H center dot center dot center dot N interactions with the ligand N atom that is not bonded to the Ni-II atom.. The layers are connected by van der Waals interactions. A Hirshfeld surface analysis indicates that the most important contacts are H center dot center dot center dot H (37.7%), C center dot center dot center dot H/H center dot center dot center dot C (14.6%), O center dot center dot center dot H/H center dot center dot center dot O (11.5%) and S center dot center dot center dot H/H center dot center dot center dot S (10.6%).