Crystal structure of a new polymeric thallium-lasalocid complex: lasalocide anion-thallium(I) containing aryl-Tl interactions

AKKURT, MEHMET; YILDIRIM, ŞAHİN; Khardli, F-Z.; Mimouni, M.; McKee, V.; Ben Hadda, T.

doi:10.3998/ark.5550190.0009.f13

Crystal structure of a new polymeric thallium-lasalocid complex: lasalocide anion-thallium(I) containing aryl-Tl interactions

Atıf İçin Kopyala

AKKURT M. , YILDIRIM Ş. , Khardli F., Mimouni M., McKee V., Ben Hadda T.

ARKIVOC, ss.121-132, 2008 (SCI İndekslerine Giren Dergi)

Basım Tarihi: 2008
Doi Numarası: 10.3998/ark.5550190.0009.f13
Dergi Adı: ARKIVOC
Sayfa Sayıları: ss.121-132

Özet

The title complex, [Tl(C34H53O8)](n), forms a pseudo individual monomer complex, in which the anionic oxygen of carboxylate group serves to neutralise the charge of Tl+, the other five O centres of the first lasalocid anionic ligand (Lasa 1) and in which this ligand is pentadentate O-ligand and bonded to a second Tl centre by using phenyl-metal coordination. A second lasalocid ligand (Lasa 2) is also pentadentate O-ligand and bridges the first Tl centre within the polymer. The monomeric unit is stabilized by strong intramolecular aryl-Tl type-metal half sandwich bonding interactions.