Solid phase extraction of Pb(II) and Cd(II) as 2,9 dimethyl-4,7-diphenyl-1,10-phenanthroline chelates on activated carbon cloth in environmental samples and their determination by flame atomic absorption spectrometry

SOYLAK M., Temeltas A.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, vol.96, no.9, pp.862-871, 2016 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 96 Issue: 9
  • Publication Date: 2016
  • Doi Number: 10.1080/03067319.2016.1209658
  • Journal Name: INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.862-871
  • Keywords: Activated carbon cloth, 2,9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline, lead, cadmium, flame atomic absorption spectrometry, WATER SAMPLES, HEAVY-METALS, MAGNETIC NANOPARTICLES, RISK-ASSESSMENT, TRACE-ELEMENTS, LEAD(II) IONS, PRECONCENTRATION, CADMIUM, ADSORPTION, REMOVAL
  • Erciyes University Affiliated: Yes

Abstract

A solid-phase extraction procedure for Pb(II) and Cd(II) as 2,9 dimethyl-4,7-diphenyl-1,10-phenanthroline complexes on activated carbon cloth (ACC) has been established. In the determination step, flame atomic absorption spectrometry (FAAS) was used. The optimum conditions for pH, type and volume of eluent, volume of sample solution, flow rates of eluent, sample solution and matrix effect were determined. For quantitative recovery of the analyte ions, refereed optimum values are as follows: amount of ACC, 0.4 g; pH, 6.0 and eluent, 10 mL 3 M HNO3. To test the accuracy of the method, a certified reference material (CRM) analysis and add-recovery methods were performed. The developed method was applied for the determination of the analyte elements in water and vegetable samples.