2-Cycloheptylidene-N-phenylhydrazine-carbothioamide


AKKURT M. , Mohamed S. K. , Mague J. T. , Hassan A. A. , Albayati M. R.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.70, 2014 (Journal Indexed in ESCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 70
  • Publication Date: 2014
  • Doi Number: 10.1107/s1600536814003948
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Abstract

In the title compound, C14H19N3S, the seven-membered cycloheptane ring adopts a chair conformation. An intramolecular N-H center dot center dot center dot N hydrogen bond [graph-set motif S(5)] is present in the N-N-C-N chain between the ring systems. An intramolecular C-H center dot center dot center dot S contact also occurs. In the crystal, pairs of molecules form centrosymmetric dimers through N-H center dot center dot center dot S hydrogen bonds [graph-set R-2(2) (8)]. These dimers are connected by C-H center dot center dot center dot S interactions with an R-2(2) (14) motif.