Rapid and efficient micro-solid phase extraction of atrazine in food and water samples using an MXene-MOF-LDH nanocomposite prior to HPLC-DAD analysis

Ahmed H. E. H., Konneh M., SOYLAK M.

Food Chemistry, cilt.521, 2026 (SCI-Expanded, Scopus) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 521
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1016/j.foodchem.2026.149862
  • Dergi Adı: Food Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, BIOSIS, Chemical Abstracts Core, Chimica, Compendex, EMBASE, MEDLINE, Academic Search Ultimate (EBSCO), Engineering Source (EBSCO)
  • Anahtar Kelimeler: Atrazine, Dispersive micro-solid phase extraction (d-μ-SPE), HPLC-DAD, V₂CTₓ/MIL-88 A/CaNiCr-LDH (MXene-MOF-LDH), Water and juice analysis
  • Erciyes Üniversitesi Adresli: Evet

Özet

A dispersive micro-solid phase extraction (d-μ-SPE) procedure was applied using a newly synthesized multilayered vanadium carbide MXene/iron-based metal–organic framework/calcium–nickel–chromium layered double hydroxide (V₂CTₓ/MIL-88 A/CaNiCr LDH) nanocomposite as the adsorbent for atrazine. Extraction parameters were optimized. The technique achieved good analytical performance, with a low limit of detection of 0.12 μg L−1, a limit of quantification of 0.40 μg L−1, a preconcentration factor of 40, and an enhancement factor of 36.8. Good accuracy was achieved, with intra- and inter-day relative standard deviation values <7.1%. Accuracy was validated by recovery experiments conducted on water and juice samples, resulting in recoveries (89% - 102%). The suggested d-μ-SPE method provides rapid extraction (12-min total), requires only 10 mg of adsorbent and 1 mL of organic solvent, and offers sensitive and reproducible atrazine determination in water and juice samples.