Synthesis, crystal structure and Hirshfeld surface analysis of (<i>Z</i>)-2-({amino[6-phenyl-3-(4-methyl-phenyl)-1,2,4-triazin-5-yl]methylidene}amino)-6-methoxybenzo[d]thiazole-4,7-diyl diacetate
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.82, ss.1140-1151, 2026 (ESCI)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 82
- Basım Tarihi: 2026
- Doi Numarası: 10.1107/s2056989026008972
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI)
- Sayfa Sayıları: ss.1140-1151
- Erciyes Üniversitesi Adresli: Evet
Özet
The stable conformation of the title molecule, C29H24N6O5S, is caused by two intramolecular N-H center dot center dot center dot N hydrogen bonds producing fused S(5) and S(6) rings. In the crystal, molecules are connected by intermolecular N-H center dot center dot center dot O interactions along the b-axis direction, forming C(9) chains. Furthermore, there are pi-pi interactions [centroid-to-centroid distance = 3.8200 (12) angstrom] between the benzene ring of the p-tolyl group and the 1,2,4-triazine ring in the same direction. As a result, the molecules form ribbons along the b-axis direction,. A Hirshfeld surface analysis was performed, showing the predominance of H...H, O center dot center dot center dot H/H center dot center dot center dot O, C center dot center dot center dot.H/H center dot center dot center dot C and N center dot center dot center dot H/H center dot center dot center dot N contacts.