Preparation and characterization of novel boron containing nanocomposites with neutron radiation shielding properties

Saltan F., ŞİRİN K., Aydin S., YILDIRIM Y.

POLYMER COMPOSITES, vol.44, no.12, pp.8627-8639, 2023 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 44 Issue: 12
  • Publication Date: 2023
  • Doi Number: 10.1002/pc.27724
  • Journal Name: POLYMER COMPOSITES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, INSPEC, Metadex, Civil Engineering Abstracts
  • Page Numbers: pp.8627-8639
  • Keywords: blending, composites, irradiation, thin films
  • Erciyes University Affiliated: Yes

Abstract

PVA/PEO/PVP-B4C and PVA/PEO/PVP-BN polymer nanocomposites were prepared using boron nitrite (BN), boron carbide (B4C), polyvinyl alcohol (PVA), polyvinylpyrrolidone (PVP), and polyethylene oxide (PEO). B4C and BN nanopowders were added to the mixture at three different percentages: 5%, 10%, and 20%. Thermal characterization was performed by differential scanning calorimetry, differential thermal analysis and thermogravimetry. Scanning electron microscopy, X-ray photoelectron spectroscopy, and X-ray diffraction were used for surface analysis and crystal structure characterization. The atomic distribution was determined by elemental analysis. Neutron shielding properties were performed at three different gamma peak areas, 1293.56 keV, 1097.33 keV, 416.86 keV, and calculated total macroscopic cross -section S-T and half-value layer. The S-T values were found to be in the range of 7.99-14.37 for all synthesized composites. B4C-doped composites show higher protection efficiency against slow thermal neutrons than BN-doped samples.