Crystal structure of 4-((1E)-1-{(2Z)-2-[ 4(4-bromophenyl)-3-phenyl-2,3-dihydro1,3-thiazol-2-ylidene] hydrazin-1-ylidene}ethyl)phenol hemihydrate


Mague J. T. , AKKURT M. , Mohamed S. K. , Hassan A. A. , Albayati M. R.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.70, 2014 (ESCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 70
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1107/s1600536814019473
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS

Özet

In the title compound, C23H18BrN3OS center dot 0.5H(2)O, the bromophenyl, phenyl and phenol rings make dihedral angles of 46.5 (1), 66.78 (8) and 15.4 (2)degrees, respectively, with the mean squares plane of the thiazolidene ring. In the crystal, the lattice water molecule is hydrogen bonded to the phenol group and makes a weaker O-H center dot center dot center dot N connection to an inversion-related molecule, forming a ring while weak pairwise C-H center dot center dot center dot S interactions involving inversion-related molecules form a second ring. Both these motifs result in the formation of two-dimensional networks lying parallel to (101).