Vibrational spectra, normal coordinate treatment and simulation of the vibrational spectra of piperazine glyoxime and its Co(III) complex


Ozpozan T. , KÜÇÜKUSTA D., BÜYÜKMUMCU Z.

JOURNAL OF MOLECULAR STRUCTURE, vol.661, pp.647-657, 2003 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 661
  • Publication Date: 2003
  • Doi Number: 10.1016/j.molstruc.2003.09.022
  • Title of Journal : JOURNAL OF MOLECULAR STRUCTURE
  • Page Numbers: pp.647-657

Abstract

Newly synthesized Co(III) complexes of piperazine glyoxime (PGO) are examined from the vibrational spectroscopy point of view. A complete interpretation of the vibrational spectra of both the ligand and the complex has been carried out on the basis of normal coordinate analysis. A valence force field has been developed for both of the compounds. The vibrational spectra of the compounds are simulated by a visual basic program prepared to run on an MS Excel data sheet. (C) 2003 Elsevier B.V. All rights reserved.