Vibrational spectra, normal coordinate treatment and simulation of the vibrational spectra of piperazine glyoxime and its Co(III) complex


Ozpozan T. , KÜÇÜKUSTA D., BÜYÜKMUMCU Z.

JOURNAL OF MOLECULAR STRUCTURE, cilt.661, ss.647-657, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 661
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1016/j.molstruc.2003.09.022
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Sayfa Sayıları: ss.647-657

Özet

Newly synthesized Co(III) complexes of piperazine glyoxime (PGO) are examined from the vibrational spectroscopy point of view. A complete interpretation of the vibrational spectra of both the ligand and the complex has been carried out on the basis of normal coordinate analysis. A valence force field has been developed for both of the compounds. The vibrational spectra of the compounds are simulated by a visual basic program prepared to run on an MS Excel data sheet. (C) 2003 Elsevier B.V. All rights reserved.