Synthesis and Single Crystal X-Ray Structure of 3,5-Diphenyl-1-(phenylacetyl)-4,5-dihydro-1H-pyrazol


Kansiz S., Tınmaz F., İLHAN I. Ö. , SARIPINAR E. , Dege N.

CRYSTALLOGRAPHY REPORTS, cilt.63, ss.937-941, 2018 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 63 Konu: 6
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1134/s1063774518060160
  • Dergi Adı: CRYSTALLOGRAPHY REPORTS
  • Sayfa Sayıları: ss.937-941

Özet

The molecule of the title pyrazole derivative, 3,5-diphenyl-1-(phenylacetyl)-4,5-dihydro-1H-pyrazol, C23H20N2O, is twisted. The compound crystallizes in the monoclinic sp. gr. I2/a with a = 15.3502(13) angstrom, b = 12.7576(8) angstrom, c = 19.625(2) angstrom, = 106.639(7)degrees, and Z = 8. In the compound, the phenyl rings form dihedral angles of 12.01(13)degrees, 80.36(8)degrees, and 86.95(9)degrees with the mean plane of the pyrazole ring (r.m.s. deviation = 0.030 angstrom). The central pyrazole ring, which approximates an envelope conformation, is almost coplanar with one of the phenyl rings. The crystal packing is stabilized by weak intermolecular C-HO hydrogen bonds.