A new strategy for the combination of supramolecular liquid phase microextraction and UV–Vis spectrophotometric determination for traces of maneb in food and water samples

SOYLAK M., Agirbas M., YILMAZ E.

Food Chemistry, cilt.338, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 338
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.foodchem.2020.128068
  • Dergi Adı: Food Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Compendex, EMBASE, Food Science & Technology Abstracts, MEDLINE, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Supramolecular solvent, Liquid phase microextraction, Maneb, Preconcentration, UV-Vis spectrophotometry, ATOMIC-ABSORPTION-SPECTROMETRY, SOLVENT-BASED MICROEXTRACTION, SIMULTANEOUS PRECONCENTRATION, DITHIOCARBAMATE FUNGICIDES, NATURAL-WATER, EXTRACTION, CHROMATOGRAPHY, VEGETABLES, SYSTEM, CADMIUM
  • Erciyes Üniversitesi Adresli: Evet

Özet

© 2020 Elsevier LtdA novel and green method was developed for enrichment of maneb (manganese ethylene-bisdithiocarbamate) with a supramolecular solvent liquid phase microextraction method. The microextraction method has been used for the first time in the literature for separation-preconcentration of maneb. 1-decanol and tetrahydrofuran were used in the supramolecular solvent formation. The Mn2+ content of maneb was extracted in the supramolecular solvent phase as 1-(2-pyridylazo)-2-naphthol complex at pH 12.0. Manganese concentration was determined by UV–Vis spectrophotometer at 555 nm. Then, the maneb concentration equivalent to manganese concentration was calculated. The analytical parameters which effective in the method, including pH, volume of reagents, and sample volume were optimized. The limit of detection and the limit of quantification values for maneb were calculated as 2.22 μg L−1 and 7.32 μg L−1, respectively. The method was successfully applied in the analysis of the maneb content of water and food samples.