1-{6-Chloro-2-[(2-chloro-6-methylquinolin-3-yl)methoxy]-4-phenylquinolin-3-yl}ethanone


Khan F. N. , Hathwar V. R. , Kumar R., Kushwaha A. K. , AKKURT M.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.66, 2010 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 66
  • Publication Date: 2010
  • Doi Number: 10.1107/s1600536810022701
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE

Abstract

In the title compound, C(28)H(20)Cl(2)N(2)O(2), the 2-chloroquinoline and 6-chloroquinoline ring systems are twisted slightly, making a dihedral angle of 4.05 (3)degrees. The dihedral angle between the 2-quinoline ring system and the phenyl ring attached to it is 74.43 (5)degrees. In the crystal structure, a pair of intermolecular C-H center dot center dot center dot O hydrogen bonds connect the molecules, forming centrosymmetric dimers with R(2)(2)(16) motifs. The dimers are further consolidated by a C-H center dot center dot center dot pi interaction and a pi-pi stacking interaction with a centroid-centroid distance of 3.6562 (10) angstrom.