Nano-clay as a solid phase microextractor of copper, cadmium and lead for ultra-trace quantification by ICP-MS

AlMasoud N., Habila M. A., Alothman Z. A., Alomar T. S., Alraqibah N., Sheikh M., ...Daha Fazla

ANALYTICAL METHODS, cilt.12, sa.41, ss.4949-4955, 2020 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 12 Sayı: 41
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1039/d0ay01343a
  • Dergi Adı: ANALYTICAL METHODS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Agricultural & Environmental Science Database, Biotechnology Research Abstracts, CAB Abstracts, Compendex, Food Science & Technology Abstracts, Veterinary Science Database
  • Sayfa Sayıları: ss.4949-4955
  • Erciyes Üniversitesi Adresli: Evet

Özet

Heavy metal microextraction and determination in daily used water is accurately achieved by applying nano-clay as an extractor. The conditions for adsorption/elution of Cu(ii), Cd(ii) and Pb(ii) were investigated by adjusting the pH of samples, sample volume and the type of eluent. The nano-clay showed superior efficiency for microextraction of Cu(ii), Cd(ii) and Pb(ii) at pH 2 using 2 mL of nitric acid (1 M) as the eluent. The microextraction procedure showed high recovery% by changing the sample volume from 15 mL to 70 mL. The preconcentration factor was found to be 37.5. The LOD and LOQ were 1.8, 1.3, and 1.9 mu g L-1 and 5.3, 3.9, and 5.7 mu g L-1 for Cu(ii), Cd(ii) and Pb(ii) respectively. The addition/recovery from different water samples showed recovery% in the range 88-105 which confirms the efficiency and the accuracy of the developed solid phase microextraction using nano-clay for enrichment of Cu(ii), Cd(ii) and Pb(ii).