1-[(Cyclohexylidene) amino]-3-(prop-2en-1-yl) thiourea


Mohamed S. K. , Mague J. T. , AKKURT M. , Hassan A. A. , Albayati M. R.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.70, pp.827-838, 2014 (Journal Indexed in ESCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 70
  • Publication Date: 2014
  • Doi Number: 10.1107/s1600536814014834
  • Title of Journal : ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Page Numbers: pp.827-838

Abstract

The asymmetric unit of the title compound, C10H17N3S, consists of three symmetry-independent molecules with distinctly different conformations, as indicated for example by the C-N-C-C torsion angles of -155.9 (3), 89.9 (3) and 81.1 (4)degrees along the bond between thiourea and allyl units. In the crystal, molecules are connected via N-H center dot center dot center dot N and N-H center dot center dot center dot S hydrogen bonds into chains extending along [110] that are further associated through C-H center dot center dot center dot N interactions into layers parallel to (001). The allyl group in one of the independent molecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6): 0.147 (6).