Copy For Citation
Ibrahimova N. Z., Tagiyev D. B., Lyatifov I. U., AKKURT M., Hasanov K. I., Bhattarai A.
Acta Crystallographica Section E: Crystallographic Communications, vol.80, no.Pt 8, pp.882-885, 2024 (ESCI)
-
Publication Type:
Article / Article
-
Volume:
80
Issue:
Pt 8
-
Publication Date:
2024
-
Doi Number:
10.1107/s2056989024006959
-
Journal Name:
Acta Crystallographica Section E: Crystallographic Communications
-
Journal Indexes:
Emerging Sources Citation Index (ESCI), Scopus
-
Page Numbers:
pp.882-885
-
Keywords:
binuclear complex, carbonyl group, carbonyl ligands, crystal structure, cyclopentadienyl ligand, Mo complex, steric effect, tert-butyl group
-
Erciyes University Affiliated:
Yes
Abstract
The dinuclear molecule of the title compound, [Mo2(C9H13)2(CO)6] or [Mo(tBuCp)(CO)3]2 wheretBu and Cp are tert-butyl and cyclopentadienyl, is centrosymmetric and is characterized by an Mo-Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, thetBuCp and the carbonyl ligands are in a transoid arrangement to each other. In the crystal, intermolecular C-H⋯O contacts lead to the formation of layers parallel to the bc plane.