Crystal structure of bis[(η5-tert-butylcyclopentadienyl)tricarbonylmolybdenum(I)](Mo-Mo)

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Ibrahimova N. Z., Tagiyev D. B., Lyatifov I. U., AKKURT M., Hasanov K. I., Bhattarai A.

Acta Crystallographica Section E: Crystallographic Communications, cilt.80, sa.Pt 8, ss.882-885, 2024 (ESCI, Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 80 Sayı: Pt 8
• Basım Tarihi: 2024
• Doi Numarası: 10.1107/s2056989024006959
• Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
• Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
• Sayfa Sayıları: ss.882-885
• Anahtar Kelimeler: crystal structure, Mo complex, carbonyl ligands, cyclopentadienyl ligand, tertbutyl group, carbonyl group, binuclear complex, steric effect
• Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
• Erciyes Üniversitesi Adresli: Evet

Özet

The dinuclear molecule of the title compound, [Mo2(C9H13)2(CO)6] or [Mo(tBuCp)(CO)3]2 wheretBu and Cp are tert-butyl and cyclopentadienyl, is centrosymmetric and is characterized by an Mo-Mo bond length of 3.2323 (3) Å. Imposed by inversion symmetry, thetBuCp and the carbonyl ligands are in a transoid arrangement to each other. In the crystal, intermolecular C-H⋯O contacts lead to the formation of layers parallel to the bc plane.