CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF 4-{2,2-DICHLORO-1-[(E)-(2,4-DICHLOROPHENYL)DIAZENYL]ETHENYL}-N,NDIMETHYLANILINE 4-{2,2-DİXLOR-1-[(E)-(2,4-DİXLORFENİL)DİAZENİL]ETENİL}-N,N-DİMETİLANİLİN KRİSTAL QURULUŞU VƏ HİRŞFELD SƏTH ANALIZI КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА И АНАЛИЗ ПОВЕРХНОСТИ ПО ХИРШФЕЛЬДУ 4-{2,2-ДИХЛОР-1-[(E)-(2,4-ДИХЛОРФЕНИЛ)ДИАЗЕНИЛ]ЭТЕНИЛ}-N,N-ДИМЕТИЛАНИЛИНА

Maharramov, A.M.; Askerova, U.F.; Ahmedova, N.E.; Askarov, A.B.; Tagiyev, D.B.; Gahramanova, Sh.I.; Shikhaliyeva, I.M.; Mukhtarova, S.H.; Akkurt, MEHMET

doi:10.32737/2221-8688-2024-4-499-508

CRYSTAL STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF 4-{2,2-DICHLORO-1-[(E)-(2,4-DICHLOROPHENYL)DIAZENYL]ETHENYL}-N,NDIMETHYLANILINE 4-{2,2-DİXLOR-1-[(E)-(2,4-DİXLORFENİL)DİAZENİL]ETENİL}-N,N-DİMETİLANİLİN KRİSTAL QURULUŞU VƏ HİRŞFELD SƏTH ANALIZI КРИСТАЛЛИЧЕСКАЯ СТРУКТУРА И АНАЛИЗ ПОВЕРХНОСТИ ПО ХИРШФЕЛЬДУ 4-{2,2-ДИХЛОР-1-[(E)-(2,4-ДИХЛОРФЕНИЛ)ДИАЗЕНИЛ]ЭТЕНИЛ}-N,N-ДИМЕТИЛАНИЛИНА

Maharramov A., Askerova U., Ahmedova N., Askarov A., Tagiyev D., Gahramanova S., ...Daha Fazla

Chemical Problems, cilt.22, sa.4, ss.499-508, 2024 (Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 22 Sayı: 4
Basım Tarihi: 2024
Doi Numarası: 10.32737/2221-8688-2024-4-499-508
Dergi Adı: Chemical Problems
Derginin Tarandığı İndeksler: Scopus, Academic Search Premier
Sayfa Sayıları: ss.499-508
Anahtar Kelimeler: Dichlorodiazadienes, Dimethylaniline group, Fingerprint, Molecule structure, Van der Waals interactions
Erciyes Üniversitesi Adresli: Evet

Özet

In the title compound, C16H13Cl4N3, the dihedral angle between the benzene rings of the dichlorophenyl and dimethylaniline groups is 50.85 (13)°. The central –N=N– unit shows an E configuration. In the crystal, molecules form parallel layers to the (100) plane by C—H···π and face-to-face π-π [centroid-to-centroid distances = 4.0538 (17) and 4.0537 (17) Å] interactions. These layers are connected by Van der Waals interactions to stabilize the crystal structure. Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from Cl···H/H···Cl (36.4%), H···H (23.3%) and C···H/H···C (15.2%) contacts.