Synthesis and crystal structure of the bis-calcimycin anion-Ni2+ complex


AKKURT M. , Melhaoui A., Ben Hadda T., Mimouni M., Yildirim S. , McKee V.

ARKIVOC, pp.154-164, 2008 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume:
  • Publication Date: 2008
  • Doi Number: 10.1016/j.str.2008.03.014
  • Title of Journal : ARKIVOC
  • Page Numbers: pp.154-164

Abstract

The X-ray structure of [Ni(calcimycin)(2)] complex shows two essentially identical conformations of the two calcimycin ligands in the dimeric association, in this ionophore family. In the title complex, the nickel (II) cation has a distorted O4N2 octahedral coordination environment.