Synthesis and crystal structure of the bis-calcimycin anion-Ni2+ complex

AKKURT, MEHMET; Melhaoui, A.; Ben Hadda, T.; Mimouni, M.; Yildirim, SEMA; McKee, V.

doi:10.1016/j.str.2008.03.014

Synthesis and crystal structure of the bis-calcimycin anion-Ni2+ complex

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AKKURT M., Melhaoui A., Ben Hadda T., Mimouni M., Yildirim S., McKee V.

ARKIVOC, pp.154-164, 2008 (SCI-Expanded)

Publication Type: Article / Article
Volume:
Publication Date: 2008
Doi Number: 10.1016/j.str.2008.03.014
Journal Name: ARKIVOC
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.154-164
Erciyes University Affiliated: Yes

Abstract

The X-ray structure of [Ni(calcimycin)(2)] complex shows two essentially identical conformations of the two calcimycin ligands in the dimeric association, in this ionophore family. In the title complex, the nickel (II) cation has a distorted O4N2 octahedral coordination environment.